How does the molecular structure affect the properties and functions of polymers at the macroscale? An interdisciplinary background across the field of Polymer Physics brings together competences essential to the success of a research project - and a bit more. The subjects of investigation range from homopolymers to copolymers and blends, for applications such as energy storage and transfer, and the automotive industry. To shed light on the interplay between the structure and dynamics of the polymers as well as their response to external stimuli, a series of advanced characterisation techniques is employed providing versatile viewpoints: they include analytical, spectroscopic, structural, thermodynamic and mechanical probes. Below you may read the latest results as published in international refereed journals. Currently I work at the Innovation Headquarters of Borealis in Linz, Austria, developing next generation polyolefin materials for addressing the global challenges of our society.

Further information is available in my full CV, in English (pdf, 359 kB) or in Greek (pdf, 449 kB).

  1. "Byproduct-free curing of a highly insulating polyethylene copolymer blend: an alternative to peroxide crosslinking", Mauri, M.; Peterson, A.; Senol, A.; Elamin, K.; Gitsas, A.; Hjertberg, T.; Matic, A.; Gkourmpis, T.; Prieto O.; Müller, C. Journal of Materials Chemistry C 2018, 6, 11292. doi: 10.1039/C8TC04494E.
    x-linking free cable insulation
  2. "Effect of film structure and morphology on the dielectric breakdown characteristics of cast and biaxially oriented polypropylene films", Rytöluoto, I.; Gitsas, A.; Pasanen, S.; Lahti, K. European Polymer Journal 2017, 95, 606. doi: 10.1016/j.eurpolymj.2017.08.051.
    Capacitor BOPP films
  3. "Nanostructuring polymeric materials by templating strategies", Knoll, W.; Caminade, A.-M.; Char, K.; Duran, H.; Feng, C. L.; Gitsas, A.; Kim, D. H.; Lau, A.; Lazzara, T. D.; Majoral, J.-P.; Steinhart, M.; Yameen, B.; Zhong, X. H. Small 2011, 7, 1384. doi: 10.1002/smll.201100026.
    nanostructured polymers
  4. "Polycyanurate nanorod arrays for optical-waveguide-based biosensing", Gitsas, A.; Yameen, B.; Lazzara, T. D.; Steinhart, M.; Duran, H.; Knoll, W. Nano Letters 2010, 10, 2173. doi: 10.1021/nl1009102.
  5. "Effects of nanoscale confinement and pressure on the dynamics of pODMA-b-ptBA-b-pODMA triblock copolymers", Gitsas, A.; Floudas, G.; Butt, H.-J.; Pakula, T.; Matyjaszewski, K. Macromolecules 2010, 43, 2453. doi: 10.1021/ma902639g.
    triblocks dynamics
  6. "Hierarchical self-assembly and dynamics of a miktoarm star chimera composed of poly(γ-benzyl-L-glutamate), polystyrene and polyisoprene", Gitsas, A.; Floudas, G.; Mondeshki, M.; Lieberwirth, I.; Spiess, H. W.; Iatrou, H.; Hadjichristidis, N.; Hirao, A. Macromolecules 2010, 43, 1874. doi: 10.1021/ma902631e.
    polypeptide Chimera
  7. "Effect of pressure on the phase bahavior and segmental dynamics in blends of polystyrene with poly(methylphenyl siloxane)", Gitsas, A.; Floudas, G.; White, R. P.; Lipson, J. E. G. Macromolecules 2009, 42, 5709. doi: 10.1021/ma900831h.
    polymer blends
  8. "Poly(γ-benzyl-L-glutamate) peptides confined to nanoporous alumina: pore diameter dependence of self-assembly and segmental dynamics", Duran, H.; Gitsas, A.; Floudas, G.; Mondeshki, M.; Steinhart, M.; Knoll, W. Macromolecules 2009, 42, 2881. doi: 10.1021/ma900119x.
  9. "Pressure dependence of the glass transition in atactic and isotactic polypropylene", Gitsas, A.; Floudas, G. Macromolecules 2008, 41, 9423. doi: 10.1021/ma8014992.
    polypropylene spherulites
  10. "Control of peptide secondary structure and dynamics in poly(γ-benzyl-L-glutamate)-b-polyalanine peptides", Gitsas, A.; Floudas, G.; Mondeshki, M.; Spiess, H. W.; Aliferis, T.; Iatrou, H.; Hadjichristidis, N. Macromolecules 2008, 41, 8072. doi: 10.1021/ma801770b.
  11. "Effect of chain topology on the self-organization and dynamics of block copolypeptides: from diblock copolymers to stars", Gitsas, A.; Floudas, G.; Mondeshki, M.; Butt, H.-J.; Spiess, H. W.; Iatrou, H.; Hadjichristidis, N. Biomacromolecules 2008, 9, 1959. doi: 10.1021/bm800221n.
    star polypeptides
  12. "Self-assembly and molecular dynamics of copolymers of γ-methyl-L-glutamate and stearyl-L-glutamate", Gitsas, A.; Floudas, G.; Dietz, M.; Mondeshki, M.; Spiess, H. W.; Wegner, G. Macromolecules 2007, 40, 8311. doi: 10.1021/ma070792i.
  13. "Self-assembly and molecular dynamics of peptide functionalized polyphenylene dendrimers", Mondeshki, M.; Mihov, G.; Graf, R.; Spiess, H. W.; Müllen, K.; Papadopoulos, P.; Gitsas, A.; Floudas, G. Macromolecules 2006, 39, 960. doi: 10.1021/ma0621270.
  14. "Role of main chain rigidity and side chain substitution on the supramolecular organization of rigid-flexible polymers", Riala, P.; Andreopoulou, A. K.; Kallitsis, J. K.; Gitsas, A.; Floudas, G. Polymer 2006, 47, 7241. doi: 10.1016/j.polymer.2006.05.079.
    rigid-flexible polymers
  15. "Self-assembly of pODMA-b-ptBA-b-pODMA triblock copolymers in bulk and on surfaces. A quantitative SAXS/AFM comparison", Wu, W.; Huang, J.; Jia, S.; Kowalewski, T.; Matyjaszewski, K.; Pakula, T.; Gitsas, A.; Floudas, G. Langmuir 2005, 21, 9721. doi: 10.1021/la051130u.
    triblock copolymers AFM
  16. "Effects of temperature and pressure on the stability and mobility of phases in rigid rod poly(p-phenylenes)", Gitsas, A.; Floudas, G.; Wegner, G. Physical Review E 2004, 69, 041802. doi: 10.1103/PhysRevE.69.041802.

We are on the front cover of the Physica Status Solidi (c) November 2011 issue

Physica Status Solidi c IWNCS10

Book Chapter
In "Functional Polymer Films"
Volume 2
Functional Polymer Films
"Nanostructured optical waveguides for thin film characterization"
Duran, H.; Lau, K. H.; Cameron, P. J.; Gitsas, A.; Steinhart, M.; Knoll, W.
Wiley-VCH, Weinheim 2011, ISBN: 978-3-527-32190-2

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